Organocatalytic Cationic Ring-Opening Polymerization of a Cyclic Hemiacetal Ester
نویسندگان
چکیده
منابع مشابه
Organocatalytic ring-opening polymerization.
Modern synthetic methods have revolutionized polymer chemistry through the development of new and powerful strategies for the controlled synthesis of complex polymer architectures.1-5 Many of these developments were spawned by new classes of transition metal catalysts for the synthesis of new polyolefin microstructures,5 the design of highly efficient families of “living” polymerization strateg...
متن کاملStereoregular Isotactic Poly(mandelic acid) via Organocatalytic Ring-Opening Polymerization of a Cyclic O-carboxyanhydride**
Poly(mandelic acid), PMA, is an aryl analogue of poly(lactic acid), PLA, and a biodegradable analogue of polystyrene. Preparation of stereoregular PMA is reported for the first time in this work using a pyridine-mandelic acid adduct (Py·MA) as an organocatalyst for the ring-opening polymerisation (ROP) of the cyclic O-carboxyanhydride, manOCA. Polymers with narrow polydispersity index and excel...
متن کاملControlled Organocatalytic Ring-Opening Polymerization of ε-Thionocaprolactone.
For the first time, the controlled ring-opening polymerization (ROP) of ε-thionocaprolactone (tnCL) is conducted. The organocatalytic ROP of tnCL occurs without carbonyl scrambling, leading to homopoly(ε-thionocaprolactone) (PtnCL). The ROP by base catalysts alone is proposed to proceed via a nucleophilic mechanism, while the addition of an H-bond donating thiourea (TU) is shown to provide exce...
متن کاملCooperative Hydrogen-Bond Pairing in Organocatalytic Ring-Opening Polymerization
Thiourea (TU)/amine base cocatalysts are commonly employed for well-controlled, highly active "living" organocatalytic ring-opening polymerizations (ROPs) of cyclic esters and carbonates. In this work, several of the most active cocatalyst pairs are shown by 1H NMR binding studies to be highly associated in solution, dominating all other known noncovalent catalyst/reagent interactions during RO...
متن کاملSynthesis of High Performance Cyclic Olefin Polymers (COPs) with Ester Group via Ring-Opening Metathesis Polymerization
Novel ester group functionalized cyclic olefin polymers (COPs) with high glass transition temperature, high transparency, good mechanical performance and excellent film forming ability have been achieved in this work via efficient ring-opening metathesis copolymerization of exo-1,4,4a,9,9a,10-hexahydro-9,10(1′,2′)-benzeno-l,4-methanoanthracene (HBM) and comonomers (5-norbornene-2-yl methylaceta...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Industrial & Engineering Chemistry Research
سال: 2016
ISSN: 0888-5885,1520-5045
DOI: 10.1021/acs.iecr.6b03114